College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of China.
Inorg Chem. 2013 Jun 17;52(12):6773-5. doi: 10.1021/ic400853r. Epub 2013 Jun 3.
A chiral heteometallic compound, [(EMIM)NaCu(1,4-ndc)2]n (1), constructed from the achiral 1,4-naphthalenedicarboxylate (1,4-ndc) ligand has been ionothermally synthesized and structurally and magnetically characterized. The chiral induction effect of the enantiopure 1-ethyl-3-methylimidazolium (EMIM) L-lactate additive in the ionothermal reaction is briefly discussed.
一种手性杂化金属配合物[(EMIM)NaCu(1,4-ndc)2]n(1)，由非手性的 1,4-萘二甲酸酯(1,4-ndc)配体构建而成，通过离子热合成并进行了结构和磁性表征。简要讨论了手性 1-乙基-3-甲基咪唑盐（EMIM）L-乳酸添加剂在离子热反应中的手性诱导效应。
