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电致变色共轭杂环聚合物及衍生物——过去十年实现长期目标的研究进展。

Electrochromic conjugated polyheterocycles and derivatives--highlights from the last decade towards realization of long lived aspirations.

机构信息

Department of Chemistry, University of California, Davis, One Shield Avenue, Davis, USA.

出版信息

Chem Commun (Camb). 2012 Jan 28;48(8):1083-101. doi: 10.1039/c1cc14992j. Epub 2011 Oct 10.

Abstract

Polymer electrochromism has been considered one of the liveliest branches of conducting polymer research, a tradition continued in the last decade. We have witnessed numerous significant advances, making commercial applications closer than ever. This feature article highlights these advances by separating them into 3 sections. The material design section emphasizes the new molecular structures that have been utilized as electrochromic materials and their promising results. The color control of polymeric electrochromics section focuses on the recent achievements towards realization of full color electrochromic display devices, lastly the advances en route commercial applications section demonstrates how some of the major drawbacks towards commercialization have been successfully addressed.

摘要

高分子电致变色被认为是导电高分子研究中最活跃的分支之一,这一传统在过去十年中得以延续。我们见证了无数重大的进展,使商业应用比以往任何时候都更加接近。本文通过将这些进展分为三个部分来突出这些进展。材料设计部分强调了作为电致变色材料而被利用的新分子结构及其有希望的结果。高分子电致变色的颜色控制部分重点介绍了实现全色电致变色显示器件的最新成果,最后,通向商业应用的进展部分展示了如何成功地解决了一些商业化的主要障碍。

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