Institut für Anorganische Chemie, Karlsruhe Institute of Technology (KIT), Engesserstrasse 15, 76131 Karlsruhe, Germany.
Angew Chem Int Ed Engl. 2011 Nov 18;50(47):11050-60. doi: 10.1002/anie.201100904. Epub 2011 Oct 11.
Ionic liquids are credited with a number of unusual properties. These include a low vapor pressure, a wide liquid-phase range, weakly coordinating properties, and a high thermal/chemical stability. These properties are certainly of great interest for inorganic synthesis and the creation of novel inorganic compounds. On the other hand, the synthesis repertoire for preparing inorganic compounds has always been broad, ranging from syntheses in solutions and melts to solid-state reactions, and from crystal growth in the gas phase to high-pressure syntheses. What new aspects can ionic liquids then add to the synthesis of inorganic compounds? This Minireview uses some early examples to show that the use of ionic liquids indeed provides access to unusual inorganic compounds.
离子液体具有许多不寻常的性质。这些性质包括低蒸气压、宽液相范围、弱配位性质和高热/化学稳定性。这些性质对于无机合成和新型无机化合物的创造确实非常有意义。另一方面，制备无机化合物的合成方法一直很广泛，包括溶液和熔体中的合成、固态反应、气相中的晶体生长和高压合成。离子液体在无机化合物的合成中还能增加哪些新的方面呢？这篇综述性文章使用了一些早期的例子来说明，使用离子液体确实可以得到不寻常的无机化合物。
