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用于 rac-β-丁内酯的立体选择性 ROP 及其与 rac-丙交酯共聚的第 4 组引发剂。

Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide.

机构信息

Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.

出版信息

Chem Commun (Camb). 2011 Dec 7;47(45):12328-30. doi: 10.1039/c1cc15265c. Epub 2011 Oct 20.

DOI:10.1039/c1cc15265c
PMID:22012272
Abstract

In this paper we demonstrate the utility of Group 4 metals for the well-controlled and stereoselective (syndiotactic) ring opening polymerization (ROP) of rac-β-butyrolactone (BBL) and their ability to form copolymers.

摘要

在本文中，我们证明了第 4 族金属在 rac-β-丁内酯（BBL）的可控和立体选择性（间同立构）开环聚合（ROP）及其形成共聚物的能力方面的应用。

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