• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

金属配合物在可生物降解聚合物合成中的应用：成就与展望

Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects.

作者信息

Mankaev Badma N, Karlov Sergey S

机构信息

Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia.

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Science, 119991 Moscow, Russia.

出版信息

Materials (Basel). 2023 Oct 13;16(20):6682. doi: 10.3390/ma16206682.

DOI:10.3390/ma16206682
PMID:37895663
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10608263/
Abstract

This review describes recent advances in the synthesis of homopolymers of lactide and related cyclic esters via ring-opening polymerization (ROP) in the presence of metal complexes based on group 1, 2, 4, 12, 13 and 14 metals. Particular attention is paid to the influence of the initiator structure on the properties of the obtaining homo- and copolymers. Also, a separate chapter is devoted to the study of metal complexes in the synthesis of copolymers of lactide and lactones. This review highlights the efforts made over the last ten years or so, and shows how main-group metals have received increasing attention in the field of the polymerization of lactide and related cyclic esters.

摘要

本综述描述了在基于第1、2、4、12、13和14族金属的金属配合物存在下，通过开环聚合（ROP）合成丙交酯及相关环状酯均聚物的最新进展。特别关注引发剂结构对所得均聚物和共聚物性能的影响。此外，还专门用一个章节研究了金属配合物在丙交酯和内酯共聚物合成中的作用。本综述重点介绍了过去十年左右所做的工作，并展示了主族金属在丙交酯及相关环状酯聚合领域如何受到越来越多的关注。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/54a6a2bc840d/materials-16-06682-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/91e620b698d1/materials-16-06682-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/9383f97e9abb/materials-16-06682-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/55eea7d4e098/materials-16-06682-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/1e7ab4111a95/materials-16-06682-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/7b3568a815de/materials-16-06682-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/09a7ed6fd6aa/materials-16-06682-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/50dd0a55c723/materials-16-06682-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/67c6264be277/materials-16-06682-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/efcc53cd165c/materials-16-06682-sch004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/54a6a2bc840d/materials-16-06682-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/91e620b698d1/materials-16-06682-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/9383f97e9abb/materials-16-06682-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/55eea7d4e098/materials-16-06682-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/1e7ab4111a95/materials-16-06682-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/7b3568a815de/materials-16-06682-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/09a7ed6fd6aa/materials-16-06682-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/50dd0a55c723/materials-16-06682-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/67c6264be277/materials-16-06682-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/efcc53cd165c/materials-16-06682-sch004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29a2/10608263/54a6a2bc840d/materials-16-06682-g012.jpg

相似文献

1
Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects.金属配合物在可生物降解聚合物合成中的应用：成就与展望
Materials (Basel). 2023 Oct 13;16(20):6682. doi: 10.3390/ma16206682.
2
Indium Catalysts for Ring Opening Polymerization: Exploring the Importance of Catalyst Aggregation.铟催化剂用于开环聚合：探究催化剂聚集的重要性。
Acc Chem Res. 2017 Nov 21;50(11):2861-2869. doi: 10.1021/acs.accounts.7b00447. Epub 2017 Oct 31.
3
Coordination Ring-Opening Polymerization of Cyclic Esters: A Critical Overview of DFT Modeling and Visualization of the Reaction Mechanisms.配位开环聚合环状酯：DFT 建模与反应机理可视化的批判性综述。
Molecules. 2019 Nov 14;24(22):4117. doi: 10.3390/molecules24224117.
4
Lewis Pair Catalysts in the Polymerization of Lactide and Related Cyclic Esters.Lewis 对催化剂在丙交酯和相关环状酯聚合中的应用。
Molecules. 2018 Jan 17;23(1):189. doi: 10.3390/molecules23010189.
5
Controlling polymer stereochemistry in ring-opening polymerization: a decade of advances shaping the future of biodegradable polyesters.控制开环聚合中的聚合物立体化学：塑造未来可生物降解聚酯的十年进展。
Chem Soc Rev. 2021 Dec 13;50(24):13587-13608. doi: 10.1039/d1cs00356a.
6
Alkali and Alkaline Earth Metal Complexes as Versatile Catalysts for Ring-Opening Polymerization of Cyclic Esters.碱金属和碱土金属配合物作为开环聚合环状酯的多功能催化剂。
Chem Rec. 2021 Aug;21(8):1898-1911. doi: 10.1002/tcr.202100148. Epub 2021 Jul 1.
7
Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures.立体控制的环状酯开环聚合：新型聚酯微结构的合成。
Chem Soc Rev. 2010 Jan;39(1):165-73. doi: 10.1039/b810065a. Epub 2009 Sep 28.
8
Beyond stereoselectivity, switchable catalysis: some of the last frontier challenges in ring-opening polymerization of cyclic esters.超越立体选择性，可切换催化：环状酯开环聚合中一些最后的前沿挑战。
Chemistry. 2015 May 26;21(22):7988-8003. doi: 10.1002/chem.201500613. Epub 2015 Apr 1.
9
Phosphazene Bases as Organocatalysts for Ring-Opening Polymerization of Cyclic Esters.磷杂环戊二烯类化合物作为开环聚合反应的有机催化剂。
Macromol Rapid Commun. 2018 Dec;39(24):e1800485. doi: 10.1002/marc.201800485. Epub 2018 Oct 1.
10
Redox-Switchable Ring-Opening Polymerization with Ferrocene Derivatives.二茂铁衍生物的氧化还原开关环开聚合。
Acc Chem Res. 2019 Feb 19;52(2):415-424. doi: 10.1021/acs.accounts.8b00523. Epub 2019 Feb 1.

引用本文的文献

1
Highly Isoselective Polymerization of rac-Lactide by Zinc Complexes of Sequential Tetradentate {ONNN} Ligands.通过连续四齿{ONNN}配体的锌配合物实现外消旋丙交酯的高异选择性聚合
ChemSusChem. 2025 Jul 1;18(13):e202500402. doi: 10.1002/cssc.202500402. Epub 2025 May 7.
2
Novel β-Benzyloxy-Substituted Copolymers of Seven-Membered Cyclic Carbonate: Ring-Opening Polymerization with L-Lactide, ε-Caprolactone and Trimethylenecarbonate.新型七元环状碳酸酯的β-苄氧基取代共聚物：与L-丙交酯、ε-己内酯和三亚甲基碳酸酯的开环聚合反应
Polymers (Basel). 2024 Nov 29;16(23):3364. doi: 10.3390/polym16233364.
3
Ti and Zr complexes bearing guanidine-phenolate ligands: coordination chemistry and polymerization studies.

本文引用的文献

1
Applications of PLA in modern medicine.聚乳酸在现代医学中的应用。
Eng Regen. 2020;1:76-87. doi: 10.1016/j.engreg.2020.08.002. Epub 2020 Sep 6.
2
Random copolymerization of trimethylene carbonate with L-lactide initiated by amine-bridged bis(phenolate) neodymium alkoxides.胺桥联双酚基钕烷氧基化合物引发的三亚甲基碳酸酯与 L-丙交酯的共聚。
Chem Commun (Camb). 2023 Jun 1;59(45):6921-6924. doi: 10.1039/d3cc01766d.
3
Gallium (III) Complexes Based on Aminobisphenolate Ligands: Extremely High Active ROP-Initiators from Well-Known and Easily Accessible Compounds.
含胍基酚盐配体的钛和锆配合物：配位化学与聚合研究
RSC Adv. 2024 Aug 16;14(35):25889-25899. doi: 10.1039/d4ra05146g. eCollection 2024 Aug 12.
4
Titanium and Vanadium Complexes of Tridentate Phenoxy-Imine and Phenoxy-Amine Ligands and Their Application in the Ring-Opening Polymerization of Cyclic Esters.三齿苯氧基-亚胺和苯氧基-胺配体的钛和钒配合物及其在环状酯开环聚合中的应用
Molecules. 2023 Dec 22;29(1):87. doi: 10.3390/molecules29010087.
基于氨基双酚配体的镓（III）配合物：高活性开环聚合引发剂，源自广为人知且易于获得的化合物。
Int J Mol Sci. 2022 Dec 9;23(24):15649. doi: 10.3390/ijms232415649.
4
The Novel Gallium Aminobisphenolate Initiator of the Ring-Opening Copolymerization of L-Lactide and ε-Caprolactone: A Computational Study.新型镓氨基双酚引发剂引发 L-丙交酯和 ε-己内酯的开环共聚：计算研究。
Int J Mol Sci. 2022 Dec 8;23(24):15523. doi: 10.3390/ijms232415523.
5
Comparison of Imine- and Phosphinimine-Supported Indium Complexes: Tuning the Reactivity for the Sequential and Simultaneous Copolymerization of Lactide and ε-Caprolactone.亚胺基和膦亚胺基负载的铟配合物的比较：调节反应性以实现丙交酯和 ε-己内酯的顺序和同时共聚。
Inorg Chem. 2022 Feb 28;61(8):3763-3773. doi: 10.1021/acs.inorgchem.2c00043. Epub 2022 Feb 16.
6
Comparative Experimental and Theoretical Study of Mg, Al and Zn Aryloxy Complexes in Copolymerization of Cyclic Esters: The Role of the Metal Coordination in Formation of Random Copolymers.环状酯共聚中镁、铝和锌芳氧基配合物的比较实验与理论研究：金属配位在无规共聚物形成中的作用
Polymers (Basel). 2020 Oct 2;12(10):2273. doi: 10.3390/polym12102273.
7
Lithium, sodium, potassium and calcium amine-bis(phenolate) complexes in the ring-opening polymerization of rac-lactide.手性丙交酯开环聚合中的锂、钠、钾和钙胺双（邻苯二酚）配合物。
Dalton Trans. 2020 Feb 7;49(5):1531-1544. doi: 10.1039/c9dt04561a. Epub 2020 Jan 13.
8
Living/controlled ring-opening (co)polymerization of lactones by Al-based catalysts with different sidearms.基于铝的带有不同侧链的催化剂引发内酯的活性/可控开环（共）聚合反应。
Dalton Trans. 2019 May 28;48(21):7167-7178. doi: 10.1039/c8dt03941k.
9
Exploring Steric Effects of Zinc Complexes Bearing Achiral Benzoxazolyl Aminophenolate Ligands in Isoselective Polymerization of rac-Lactide.探索手性苯并恶唑基氨苯酚配体锌配合物在 rac-丙交酯等规聚合中的空间位阻效应。
Inorg Chem. 2018 Sep 4;57(17):11240-11251. doi: 10.1021/acs.inorgchem.8b01839. Epub 2018 Aug 22.
10
Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization.克服用于等规选择性丙交酯聚合的铟席夫碱催化剂中的聚集现象。
Chem Sci. 2015 Sep 1;6(9):5284-5292. doi: 10.1039/c5sc01584g. Epub 2015 Jul 6.