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巴西圣保罗沿海地区海洋哺乳动物的鲸脂中的多溴二苯醚。

PBDEs in the blubber of marine mammals from coastal areas of São Paulo, Brazil, southwestern Atlantic.

机构信息

Geochemical and Environmental Research Group, College of Geosciences, Texas A&M University, 833 Graham Road, College Station, TX 77845, USA.

出版信息

Mar Pollut Bull. 2011 Dec;62(12):2666-70. doi: 10.1016/j.marpolbul.2011.09.024. Epub 2011 Oct 19.

Abstract

Limited information is available in the literature on the levels of brominated flame retardants in the southern hemisphere. This study presents concentrations of polybrominated diphenyl ethers (PBDEs) in the blubber of small cetaceans from the coast of São Paulo (Brazil), southwestern Atlantic. PBDE levels were highest in Stenella frontalis (770 ng g(-1) lipid) followed by Steno bredanensis (475 ng g(-1) lipid), Sotalia guianensis (65.6 ng g(-1) lipid), Tursiopstruncatus (64.2 ng g(-1) lipid) and Pontoporia blainvillei (60.3 ng g(-1) lipid). In general, continental shelf individuals exhibited higher contamination than inshore animals. This might be related to larger prey items consumed by continental shelf dolphins. The pattern of contamination indicates that Penta-BDE commercial mixtures are a major source of PBDEs to top predators in the southwestern Atlantic. Congeners found in Octa-BDE formulations were not detected in the investigated animals.

摘要

有关南半球溴化阻燃剂水平的文献资料有限。本研究报告了南大西洋圣保罗海岸(巴西)小型鲸目动物(海豚)鲸脂中的多溴二苯醚(PBDEs)浓度。在研究的几种海豚中,Stenella frontalis(770ng/g 脂)的 PBDE 浓度最高,其次是 Steno bredanensis(475ng/g 脂)、Sotalia guianensis(65.6ng/g 脂)、Tursiopstruncatus(64.2ng/g 脂)和 Pontoporia blainvillei(60.3ng/g 脂)。一般来说,大陆架个体的污染程度高于近岸动物。这可能与大陆架海豚食用的较大猎物有关。污染模式表明,五溴商业混合物是南大西洋顶级捕食者 PBDEs 的主要来源。在调查的动物中没有发现八溴配方中的同系物。

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