BOP 介导的一锅法合成 C5 对称的大环吡啶酮五聚体。
BOP-mediated one-pot synthesis of C5-symmetric macrocyclic pyridone pentamers.
机构信息
Faculty of Light Industry and Chemical Engineering, Guang Dong University of Technology, Guang Dong, 510006, China.
出版信息
Chem Commun (Camb). 2011 Dec 14;47(46):12488-90. doi: 10.1039/c1cc14377h. Epub 2011 Oct 21.
PMID:22016882
Abstract
We report here, for the first time, the BOP-mediated one-pot macrocyclization that is facilitated and guided by internally placed intramolecular H-bonds to allow for the highly selective formation of five-residue cation-binding macrocycles.
摘要
我们在这里首次报告了 BOP 介导的一锅法大环化反应，该反应由内部放置的分子内氢键促进和导向，允许高度选择性地形成五残基阳离子结合大环。
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