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在其周边官能化的大环五聚体作为潜在的结构单元。

Macrocyclic pentamers functionalised around their periphery as potential building blocks.

作者信息

Nam Seong, Ware David C, Brothers Penelope J

机构信息

School of Chemical Sciences, University of Auckland Private Bag 92019 Auckland 1142 New Zealand

MacDiarmid Institute for Advanced Materials and Nanotechnology New Zealand.

出版信息

RSC Adv. 2019 Mar 14;9(15):8389-8393. doi: 10.1039/c8ra10446h. eCollection 2019 Mar 12.

DOI:10.1039/c8ra10446h
PMID:35518683
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9061804/
Abstract

The elaboration of a five-fold symmetric macrocyclic aromatic pentamer bearing peripheral benzyloxy and hydroxyl groups is described. These could be used to explore further functionalisation for use as pentagonal building blocks. The internal fluorine-substituted macrocycle has been prepared a one-pot procedure which is an improvement on the stepwise chain growth approach reported in the literature.

摘要

描述了一种带有外围苄氧基和羟基的五重对称大环芳族五聚体的制备方法。这些可用于进一步探索用作五边形构建块的功能化。内部氟取代的大环已通过一锅法制备，这是对文献中报道的逐步链增长方法的改进。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12fb/9061804/116a444e269e/c8ra10446h-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12fb/9061804/7056e2d0519c/c8ra10446h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12fb/9061804/1e9e906bd54e/c8ra10446h-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12fb/9061804/116a444e269e/c8ra10446h-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12fb/9061804/7056e2d0519c/c8ra10446h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12fb/9061804/1e9e906bd54e/c8ra10446h-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12fb/9061804/116a444e269e/c8ra10446h-s2.jpg

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本文引用的文献

1
Campestarenes: new building blocks with 5-fold symmetry.轮环藤烯类化合物：具有五重对称的新构筑基元。
Org Biomol Chem. 2018 Sep 11;16(35):6460-6469. doi: 10.1039/c8ob00957k.
2
Ca-NIR: a ratiometric near-infrared calcium probe based on a dihydroxanthene-hemicyanine fluorophore.Ca-NIR：一种基于二羟基蒽-半菁荧光团的比率型近红外钙探针。
Chem Commun (Camb). 2017 Jun 1;53(45):6117-6120. doi: 10.1039/c7cc02418e.
3
Frontiers of supramolecular chemistry at solid surfaces.固体表面的超分子化学前沿。
Chem Soc Rev. 2017 May 9;46(9):2520-2542. doi: 10.1039/c7cs00113d.
4
The Rich Tautomeric Behavior of Campestarenes.campestarenes的丰富互变异构行为。
Chemistry. 2016 Dec 5;22(49):17657-17672. doi: 10.1002/chem.201603231. Epub 2016 Oct 27.
5
Anion-induced dimerization of 5-fold symmetric cyanostars in 3D crystalline solids and 2D self-assembled crystals.阴离子诱导的五重对称氰基星在三维晶体固体和二维自组装晶体中的二聚化。
Chem Commun (Camb). 2014 Sep 7;50(69):9827-30. doi: 10.1039/c4cc03725a.
6
Self-assembly of hydrogen-bonded two-dimensional quasicrystals.氢键二维准晶的自组装。
Nature. 2014 Mar 6;507(7490):86-9. doi: 10.1038/nature12993.
7
A pentagonal cyanostar macrocycle with cyanostilbene CH donors binds anions and forms dialkylphosphate [3]rotaxanes.一个具有氰基二苯乙烯 CH 供体的五边形氰星大环配合物可以结合阴离子并形成二烷基磷酸酯[3]轮烷。
Nat Chem. 2013 Aug;5(8):704-10. doi: 10.1038/nchem.1668. Epub 2013 Jun 16.
8
Folding-promoted TBAX-mediated selective demethylation of methoxybenzene-based macrocyclic aromatic pentamers.折叠促进的 TBAX 介导的基于甲氧基苯的大环芳香五聚体的选择性去甲基化。
Org Biomol Chem. 2012 Jun 7;10(21):4164-71. doi: 10.1039/c2ob25160d. Epub 2012 Mar 29.
9
Folding-promoted TBACl-mediated chemo- and regioselective demethylations of methoxybenzene-based macrocyclic pentamers.折叠促进的三苯甲基氯介导的基于甲氧基苯的大环五聚体的化学和区域选择性脱甲基化。
Org Lett. 2011 Dec 2;13(23):6212-5. doi: 10.1021/ol202658p. Epub 2011 Nov 2.
10
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