Department of Nanobio Materials and Electronics and School of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagiro (1 Oryong-dong), Buk-gu, Gwangju 500712, Republic of Korea.
Chem Commun (Camb). 2012 Jan 21;48(6):826-8. doi: 10.1039/c1cc14927j. Epub 2011 Oct 21.
Poly(n-hexyl isocyanate) (PHIC) with varying molecular weights were synthesized using a chiral initiator and chiral terminator by living anionic polymerization. In such PHICs, chirality of the initiator plays a decisive role in determining the helical sense of the entire polymeric chain, whereas chirality of the terminator plays a supportive role.
采用手性引发剂和手性终止剂通过活性阴离子聚合合成了不同分子量的聚己基异氰酸酯（PHIC）。在这种 PHIC 中，引发剂的手性在决定整个聚合物链的螺旋构象方面起着决定性的作用，而终止剂的手性则起着辅助作用。
