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氟化乙烯碳酸酯作为可充电钠离子电池电解液添加剂。

Fluorinated ethylene carbonate as electrolyte additive for rechargeable Na batteries.

出版信息

ACS Appl Mater Interfaces. 2011 Nov;3(11):4165-8. doi: 10.1021/am200973k. Epub 2011 Nov 1.

DOI:10.1021/am200973k
PMID:22026720
Abstract

Fluoroethylene carbonate is an efficient electrolyte additive to improve the reversibility of electrochemical sodium insertion for hard-carbon and NaNi(1/2)Mn(1/2)O(2) electrodes in aprotic Na cells. The additive is also capable of the electrochemical deposition/dissolution of metallic Na with higher reversibility because of improved passivation and suppression of side reactions between Na metal and propylene carbonate solution containing Na salts.

摘要

氟代碳酸乙烯酯是一种有效的电解质添加剂，可提高硬碳和 NaNi(1/2)Mn(1/2)O(2)电极在非质子 Na 电池中的电化学钠嵌入可逆性。由于改善了钝化和抑制了含 Na 盐的碳酸丙烯酯溶液与 Na 金属之间的副反应，该添加剂还能够实现更具可逆性的金属 Na 的电沉积/溶解。

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