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新型、低成本、高可溶性 n 型半导体:四氮杂蒽四酯。

Novel, low-cost, highly soluble n-type semiconductors: tetraazaanthracene tetraesters.

机构信息

Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00 664 Warszawa, Poland.

出版信息

Org Lett. 2011 Nov 18;13(22):6090-3. doi: 10.1021/ol2025789. Epub 2011 Oct 26.

Abstract

New tetraester derivatives of 1,4,5,8-tetraazaanthracene have been prepared and characterized by spectroscopic and electrochemical techniques. The LUMO level of the compounds is close to -4 eV (the so-called air operating stability border in n-channel field effect transistors). Tetraesters were obtained with reasonable yields without the necessity of using high-quality reactants or solvents, resulting in their low cost.

摘要

新型 1,4,5,8-四氮杂蒽的四酯衍生物已通过光谱和电化学技术进行了制备和表征。这些化合物的 LUMO 能级接近-4 eV(即 n 沟道场效应晶体管中的所谓空气工作稳定性边界)。这些四酯以合理的产率获得,而无需使用高质量的反应物或溶剂,从而降低了成本。

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