Toyota Central Research and Development Laboratories, Inc., Nagakute, Aichi 480-1192, Japan.
Chem Commun (Camb). 2011 Dec 21;47(47):12664-6. doi: 10.1039/c1cc16160a. Epub 2011 Oct 31.
Highly selective photoelectrochemical CO(2) reduction (>80% selectivity) in water was successfully achieved by combining Cu(2)ZnSnS(4) (CZTS) with a metal-complex electrocatalyst. CZTS, a sulfide semiconductor that possesses a narrow band gap and consists of earth-abundant elements, is demonstrated to be a candidate photoabsorber for a CO(2) reduction hybrid photocatalyst.
通过将 Cu(2)ZnSnS(4) (CZTS) 与金属配合物电催化剂结合，成功实现了在水中具有高选择性的光电化学 CO(2)还原（>80%选择性）。CZTS 是一种具有窄带隙且由丰富元素组成的硫化半导体，被证明是 CO(2)还原混合光催化剂的候选光吸收剂。
