Catalonia Energy Research Institute (IREC) , 08930 Barcelona, Spain.
J Am Chem Soc. 2014 Jul 2;136(26):9236-9. doi: 10.1021/ja502076b. Epub 2014 Jun 19.
Cu2ZnSnS4, based on abundant and environmental friendly elements and with a direct band gap of 1.5 eV, is a main candidate material for solar energy conversion through both photovoltaics and photocatalysis. We detail here the synthesis of quasi-spherical Cu2ZnSnS4 nanoparticles with unprecedented narrow size distributions. We further detail their use as seeds to produce CZTS-Au and CZTS-Pt heterostructured nanoparticles. Such heterostructured nanoparticles are shown to have excellent photocatalytic properties toward degradation of Rhodamine B and hydrogen generation by water splitting.
Cu2ZnSnS4，基于丰富且环保的元素，具有 1.5eV 的直接带隙，是通过光电子学和光催化将太阳能转化的主要候选材料。我们详细介绍了具有空前窄尺寸分布的准球形 Cu2ZnSnS4 纳米粒子的合成。我们进一步详细介绍了它们作为种子来生产 CZTS-Au 和 CZTS-Pt 异质结构纳米粒子的用途。这种异质结构纳米粒子显示出对罗丹明 B 的降解和水分解制氢的优异光催化性能。
