Suppr超能文献

链状聚[[三水合镍(II)]-μ-5-羧基苯-1,3-二羧酸根合-κO:O]

catena-Poly[[triaqua-nickel(II)]-μ-5-carb-oxy-benzene-1,3-dicarboxyl-ato-κO:O].

作者信息

Yao Xing-Jun, Yuan Qian

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1331-2. doi: 10.1107/S1600536811035227. Epub 2011 Sep 14.

Abstract

In the title compound, Ni(C(9)H(4)O(6))(H(2)O)(3), the Ni(II) ion has a distorted NiO(5) square-pyramidal geometry, the maximum deviation from the least-squares plane formed by the basal atoms being 0.9351 (13) Å. The basal plane is formed by two O atoms from carboxyl-ate residues of the 5-carb-oxy-benzene-1,3-dicarboxyl-ate ligand and by two O atoms from water mol-ecules. The O atom of the third water mol-ecule is axially positioned, 1.7890 (19) Å perpendicular to the basal plane. The 5-carb-oxy-benzene-1,3-dicarboxyl-ate ligand bridges the metal atoms, forming a polymeric chain along the b axis. O-H⋯O hydrogen bonds between the water mol-ecules and carboxyl-ate groups stabilize the crystal structure.

摘要

在标题化合物[Ni(C₉H₄O₆)(H₂O)₃]ₙ中,Ni(II)离子具有扭曲的NiO₅四方锥几何构型,与由基底原子形成的最小二乘平面的最大偏差为0.9351(13) Å。基底平面由来自5-羧基苯-1,3-二羧酸酯配体羧酸盐残基的两个O原子和来自水分子的两个O原子形成。第三个水分子的O原子轴向定位,垂直于基底平面1.7890(19) Å。5-羧基苯-1,3-二羧酸酯配体桥接金属原子,沿b轴形成聚合物链。水分子与羧酸盐基团之间的O—H⋯O氢键稳定了晶体结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a8/3201226/a4ca479051a0/e-67-m1331-fig1.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验