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（μ-甲酰基-κO:O'）双[二羰基（η-环戊二烯基）铁（II）]四氟硼酸盐

(μ-Formato-κO:O')bis-[dicarbon-yl(η-cyclo-penta-dien-yl)iron(II)] tetra-fluoridoborate.

作者信息

M'thiruaine Cyprian M, Friedrich Holger B, Changamu Evans O, Omondi Bernard

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1252. doi: 10.1107/S1600536811032764. Epub 2011 Aug 17.

DOI:10.1107/S1600536811032764
PMID:22058865
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3200969/
Abstract

In the structure of the title compound [Fe(2)(C(5)H(5))(2)(CHO(2))(CO)(4)]BF(4), each Fe(II) atom is coordinated in a pseudo-octa-hedral three-legged piano-stool fashion. The cyclo-penta-dienyl ligand occupies three fac coordination sites while the two carbonyl ligands and formate O atom occupy the remaining three sites.

摘要

在标题化合物[Fe₂(C₅H₅)₂(CHO₂)(CO)₄]BF₄的结构中，每个Fe(II)原子以假八面体三腿钢琴凳构型配位。环戊二烯基配体占据三个面式配位位点，而两个羰基配体和甲酸根O原子占据其余三个位点。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec30/3200969/93a35cc87e30/e-67-m1252-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec30/3200969/93a35cc87e30/e-67-m1252-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec30/3200969/93a35cc87e30/e-67-m1252-fig1.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m485. doi: 10.1107/S1600536811010154. Epub 2011 Mar 26.
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