二羰基（η⁵-环戊二烯基）（2,3-二溴丙胺-κN）铁（II）四氟硼酸盐
Dicarbon-yl(η(5)-cyclo-penta-dien-yl)(2,3-di-bromo-propanamine-κN)iron(II) tetra-fluoridoborate.
作者信息
M'thiruaine Cyprian M, Friedrich Holger B, Changamu Evans O, Fernandes Manuel A
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m932. doi: 10.1107/S1600536812025925. Epub 2012 Jun 16.
The title compound, Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2) contains an Fe(II) cation with a three-legged piano-stool coordination. The NH(2)CH(2)CHBrCH(2)Br ligand contains a chiral carbon atom. The Fe-N bond length is 2.011 (3) Å and the Fe-Cp centroid distance is 1.7189 (5) Å. In the crystal, the ions are linked via two N-H⋯F inter-actions and a weak N-H⋯Br inter-action.
标题化合物Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2)包含一个具有三脚架式钢琴凳配位的Fe(II)阳离子。NH(2)CH(2)CHBrCH(2)Br配体含有一个手性碳原子。Fe-N键长为2.011 (3) Å，Fe-Cp质心距离为1.7189 (5) Å。在晶体中，离子通过两个N-H⋯F相互作用和一个弱的N-H⋯Br相互作用相连。
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