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5-苄基-5H-吡啶并[3,2-b]吲哚

5-Benzyl-5H-pyrido[3,2-b]indole.

作者信息

Letessier Julien, Schollmeyer Dieter, Detert Heiner

机构信息

University Mainz, Duesbergweg 10-14, 55099 Mainz, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2341. doi: 10.1107/S1600536811032107. Epub 2011 Aug 17.

DOI:10.1107/S1600536811032107
PMID:22058962
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3200621/
Abstract

The title compound, C(18)H(14)N(2), was prepared by twofold Pd-catalyzed aryl-amination of a cyclic pyrido-benzo-iodo-lium salt. In the crystal, two mol-ecules of 9-benzyl-δ-carboline form centrosymmetrical dimers with distances of 3.651 (2) Å between the centroids of the pyridine rings and 3.961 (2) Å between the centroids of the pyrrole and pyridine rings. The phenyl rings point to the other mol-ecule in the dimer and the carboline core is essentially planar [maximum deviation of 0.027 (2) Å].

摘要

标题化合物C(18)H(14)N(2)是通过对环状吡啶并苯并碘鎓盐进行两次钯催化的芳基胺化反应制备的。在晶体中，两个9-苄基-δ-咔啉分子形成中心对称二聚体，吡啶环质心之间的距离为3.651 (2) Å，吡咯环与吡啶环质心之间的距离为3.961 (2) Å。苯环指向二聚体中的另一个分子，咔啉核心基本呈平面状[最大偏差为0.027 (2) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a02d/3200621/6ca97d08f3c3/e-67-o2341-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a02d/3200621/6ca97d08f3c3/e-67-o2341-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a02d/3200621/6ca97d08f3c3/e-67-o2341-fig1.jpg

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