Yu Rui-Jin, Deng Bin
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1253. doi: 10.1107/S1600536811032399. Epub 2011 Aug 17.
A pair of linear cyanamide (NCNH(2)) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the Cu(II) atom into a mononuclear unit, [Cu(NO(3))(2)(C(9)H(8)N(2)O)(2)(NCNH(2))(2)]. The coordination polyhedron of the Cu atom is an elongated octa-hedron distorted by Jahn-Teller effects. Inter-molecular O-H⋯O, O-H⋯N, N-H⋯O and N-H⋯N hydrogen-bonding inter-actions link these units into a three-dimensional supra-molecular architecture.
一对线性氰胺(NCNH₂)配体、两个单齿4-(1H-咪唑-1-基)苯酚(L)配体和两个硝酸根阴离子将铜(II)原子连接成一个单核单元[Cu(NO₃)₂(C₉H₈N₂O)₂(NCNH₂)₂]。铜原子的配位多面体是一个因 Jahn-Teller 效应而扭曲的拉长八面体。分子间的 O-H⋯O、O-H⋯N、N-H⋯O 和 N-H⋯N 氢键相互作用将这些单元连接成三维超分子结构。