Chantrapromma Suchada, Jansrisewangwong Patcharaporn, Chanawanno Kullapa, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2221-2. doi: 10.1107/S1600536811029679. Epub 2011 Aug 2.
The asymmetric unit of the title compound, C(16)H(16)N(2)O(2)·2H(2)O, contains one half-mol-ecule of diphenol and one water mol-ecule. The complete diphenol mol-ecule is generated by a crystallographic inversion centre. In the mol-ecule, the central C(meth-yl)-C=N-N=C-C(meth-yl) plane makes a dihedral angle of 8.88 (6)° with its adjacent benzene ring. In the crystal, the components are linked by O-H⋯N and O-H⋯O hydrogen bonds into a three-dimensional network. The crystal structure is further stabilized by a weak C-H⋯π inter-action.
标题化合物C(16)H(16)N(2)O(2)·2H(2)O的不对称单元包含半个双酚分子和一个水分子。完整的双酚分子由一个晶体学倒转中心产生。在分子中,中心的C(甲基)-C=N-N=C-C(甲基)平面与其相邻的苯环形成8.88 (6)°的二面角。在晶体中,各组分通过O-H⋯N和O-H⋯O氢键连接成三维网络。晶体结构通过弱的C-H⋯π相互作用进一步稳定。