（乙酰丙酮根-κO,O'）双-[5-甲氧基-2-（萘并[1,2-d][1,3]恶唑-2-基）苯基-κC,N]铱（III）
(Acetyl-acetonato-κO,O')bis-[5-meth-oxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κC,N]iridium(III).
作者信息
Li Song, Yin Guo-Jie, Wang Shi-Min, Zhou Yuan-Yuan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1343. doi: 10.1107/S1600536811035690. Epub 2011 Sep 14.
Abstract
In the title compound, [Ir(C(18)H(12)NO(2))(2)(C(5)H(7)O(2))], the Ir atom is O,O'-chelated by the acetyl-acetonate group and C,N-chelated by the 2-aryl-naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa-hedral geometry. Intra-molecular C-H⋯O hydrogen bonds occur. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into columns parallel to the b axis.
摘要
在标题化合物[Ir(C₁₈H₁₂NO₂)₂(C₅H₇O₂)]中，Ir原子通过乙酰丙酮基团进行O,O'-螯合，并通过2-芳基萘并[1,2-d]恶唑基团进行C,N-螯合。六配位的金属原子呈现出扭曲的八面体几何构型。分子内存在C—H⋯O氢键。在晶体中，分子间的C—H⋯O氢键将分子连接成平行于b轴的柱体。
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