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[3-氯-N'-(2-氧代萘-1-基亚甲基)苯甲酰肼基]甲醇(甲醇基)氧钒(V)

[3-Chloro-N'-(2-oxidonaphthalen-1-yl-methylidene)benzohydrazidato]methanol(methanolato)oxidovanadium(V).

作者信息

Wang Fu-Ming

机构信息

Department of Chemistry, Dezhou University, Dezhou Shandong 253023, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1254. doi: 10.1107/S1600536811032703. Epub 2011 Aug 17.

DOI:10.1107/S1600536811032703
PMID:22065698
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3200794/
Abstract

In the title complex, [V(C(18)H(11)ClN(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) ion is coordinated by a tridendate 3-chloro-N'-(2-oxidonaphthalen-1-ylmethylidene)benzohydrazidate ligand, one oxido ligand and by O atoms from a methanol and a methoxide ligand, forming a distorted octa-hedral geometry. The dihedral angle between the benzene ring and the naphthyl-ene ring system is 6.4 (3)°. The deviation of the V(V) ion from the plane defined by the three donor atoms of the tridentate ligand and the meth-oxy O atom towards the oxido O atom is 0.323 (2) Å. In the crystal, pairs of inter-molecular O-H⋯N hydrogen bonds form centrosymmetric dimers.

摘要

在标题配合物[V(C₁₈H₁₁ClN₂O₂)(CH₃O)O(CH₃OH)]中，V(V)离子由一个三齿的3-氯-N'-(2-氧化萘-1-基亚甲基)苯甲酰肼配体、一个氧化配体以及来自甲醇和甲氧基配体的O原子配位，形成扭曲的八面体几何构型。苯环与萘环系统之间的二面角为6.4 (3)°。V(V)离子从由三齿配体的三个供体原子和甲氧基O原子所定义的平面朝向氧化O原子的偏差为0.323 (2) Å。在晶体中，分子间O—H⋯N氢键对形成中心对称的二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f642/3200794/f67d04e3c9d3/e-67-m1254-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f642/3200794/acbb38a6fbe4/e-67-m1254-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f642/3200794/f67d04e3c9d3/e-67-m1254-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f642/3200794/acbb38a6fbe4/e-67-m1254-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f642/3200794/f67d04e3c9d3/e-67-m1254-fig2.jpg

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本文引用的文献

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