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反式-羰基二氯双[三（萘-1-基）膦-κP]铑（I）丙酮三水合物

trans-Carbonyl-chloridobis[tris(naph-thalen-1-yl)-phosphane-κP]rhodium(I) acetone trisolvate.

作者信息

Meijboom Reinout

机构信息

Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1438. doi: 10.1107/S1600536811038505. Epub 2011 Sep 30.

DOI:10.1107/S1600536811038505
PMID:22065702
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201328/
Abstract

In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh-Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.

摘要

在标题化合物反式-[RhCl{P(C₁₀H₇)₃}₂(CO)]·3C₃H₆O中，其中P(C₁₀H₇)₃是三萘基膦，Rh-P键长为2.3360 (10) Å和2.3258 (10) Å，而Rh-Cl键长为2.3525 (11) Å。Rh原子周围的配位呈略微扭曲的平面正方形排列。

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