Ogutu Hezron, Meijboom Reinout
Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, 2006 Johannesburg, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m394. doi: 10.1107/S1600536812008148. Epub 2012 Mar 10.
The title compound, [Rh(C(5)H(7)O(2))(C(30)H(21)P)(CO)]·0.5C(3)H(6)O, has two different complex molecules in the asymmetric unit, with the Rh(I) atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol-ecules with one acetone solvent mol-ecule sitting at the centre.
标题化合物[Rh(C₅H₇O₂)(C₃₀H₂₁P)(CO)]·0.5C₃H₆O在不对称单元中有两个不同的复杂分子,Rh(I)原子处于略微扭曲的平面正方形配位环境中。这些分子以两个单体分子的形式堆积,一个丙酮溶剂分子位于中心位置。