Sustainable Technology Division, National Risk Management Research Laboratory, U. S. Environmental Protection Agency, Cincinnati, Ohio 45268, USA.
Chem Soc Rev. 2012 Feb 21;41(4):1559-84. doi: 10.1039/c1cs15204a. Epub 2011 Nov 10.
Microwave, ultrasound, sunlight and mechanochemical mixing can be used to augment conventional laboratory techniques. By applying these alternative means of activation, a number of chemical transformations have been achieved thereby improving many existing protocols with superior results when compared to reactions performed under traditional conditions. The purpose of this critical review is to highlight the advances in this general area by presenting such newer applications in organic synthesis (175 references).
微波、超声、阳光和机械化学搅拌均可用于增强常规实验室技术。通过应用这些替代的激活手段,已经实现了许多化学转化,从而改进了许多现有的方案,与在传统条件下进行的反应相比,得到了更好的结果。本文的目的是通过介绍有机合成中的这些较新应用(175 篇参考文献),突出该领域的进展。