College of Science, China Agricultural University, Beijing 100193, PR China.
Ecotoxicol Environ Saf. 2012 Mar;77:52-6. doi: 10.1016/j.ecoenv.2011.10.017. Epub 2011 Nov 9.
The residue levels and dissipation rate of fenpropidin in wheat and soil were investigated by LC-MS/MS and GC-MS, respectively. The dissipation rates of fenpropidin were described using first-order kinetics and its half-life ranged from 3.1 to 3.3 days in wheat plants and 13.4-16.5 days in soils. During harvest time, the terminal residues of fenpropidin in wheat were below the EUs maximum residue limit (MRL, 0.5 mg kg(-1)) when collected 20 days after the final application, which suggested that the use of this fungicide was safe for humans. The residues persistence varied between two geographically separated experimental sites, indicating that it might be influenced by climate, soil properties and growth dilution factor. These results would be helpful in setting MRL guidance of fenpropidin in wheat in China.
采用 LC-MS/MS 和 GC-MS 分别研究了在小麦和土壤中,丙森锌的残留水平及其消解动态。丙森锌在小麦植株和土壤中的消解均符合一级动力学方程,半衰期分别为 3.1-3.3 天和 13.4-16.5 天。末次施药 20 天后收获,小麦中丙森锌的最终残留量均低于欧盟最大残留限量(MRL,0.5mg/kg),表明该杀菌剂对人体是安全的。在两个地理位置不同的实验点,丙森锌的残留持久性存在差异,这表明其可能受气候、土壤特性和生长稀释因子的影响。这些结果将有助于在中国制定小麦中丙森锌的 MRL 指导值。