松香衍生的叔胺-硫脲催化的高对映选择性傅克烷基化反应：具有抗癌活性的改性色满的合成。
Highly enantioselective Friedel-Crafts alkylation reaction catalyzed by rosin-derived tertiary amine-thiourea: synthesis of modified chromanes with anticancer potency.
机构信息
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
出版信息
Chem Commun (Camb). 2012 Jan 11;48(3):446-8. doi: 10.1039/c1cc14379d. Epub 2011 Nov 14.
PMID:22080190
Abstract
We present herein for the first time the synthesis and preliminary biological evaluation of various modified chromanes via a rosin-derived tertiary amine-thiourea-catalyzed highly enantioselective Friedel-Crafts alkylation reaction.
摘要
本文首次通过松香衍生的叔胺-硫脲催化的高对映选择性 Friedel-Crafts 烷基化反应，合成并初步评价了各种修饰的色满。
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