使用硼翁阳离子等价物的 N-导向脂肪族 C-H 硼化反应。
N-Directed aliphatic C-H borylation using borenium cation equivalents.
机构信息
Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.
出版信息
J Am Chem Soc. 2011 Dec 21;133(50):20056-9. doi: 10.1021/ja208093c. Epub 2011 Nov 23.
Abstract
Highly electrophilic boron cations derived from hindered amine borane complexes have been shown to undergo intramolecular aliphatic C-H borylation.
摘要
受阻伯胺硼烷配合物衍生的高亲电性硼阳离子已被证明可进行分子内脂肪族 C-H 硼化反应。
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