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1,1',2,2',3,3',4,4'-八甲基二茂铁鎓 2,5-二溴-4-羟基-3,6-二氧代环己-1,4-二烯-1-醇盐

1,1',2,2',3,3',4,4'-Octa-methyl-ferro-cenium 2,5-dibromo-4-hy-droxy-3,6-dioxocyclo-hexa-1,4-dien-1-olate.

作者信息

Mochida Tomoyuki

机构信息

Department of Chemistry, Graduate School of Science, Kobe University, Rokkodai, Nada, Hyogo 657-8501, Japan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1012. doi: 10.1107/S1600536811025499. Epub 2011 Jul 2.

DOI:10.1107/S1600536811025499
PMID:22090810
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212108/
Abstract

In the title salt, octa-methyl-ferrocenium bromanilate, Fe(C(9)H(13))(2), the Fe atom and the bromanilate anion lie on a mirror plane. The octa-methyl-ferrocenium cation adopts an eclipsed conformation. An intra-molecular O-H⋯O hydrogen bond is present in the bromanilate anion. In the crystal, the cations and anions are stacked alternately, forming a one-dimensional columnar structure along [010].

摘要

在标题盐八甲基二茂铁溴苯胺盐Fe(C₉H₁₃)₂中，铁原子和溴苯胺阴离子位于一个镜面平面上。八甲基二茂铁阳离子呈重叠构象。溴苯胺阴离子中存在分子内O—H⋯O氢键。在晶体中，阳离子和阴离子交替堆积，沿[010]方向形成一维柱状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee2a/3212108/a822277383e8/e-67-m1012-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee2a/3212108/cd0557ae4c2e/e-67-m1012-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee2a/3212108/a822277383e8/e-67-m1012-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee2a/3212108/cd0557ae4c2e/e-67-m1012-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee2a/3212108/a822277383e8/e-67-m1012-fig2.jpg

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本文引用的文献

1
Charge-transfer complexes from decamethylferrocene and 1,4-quinone derivatives: neutral-ionic phase diagrams for metallocene complexes.二茂铁及其醌衍生物的电子转移复合物：茂金属配合物的中性-离子相图。
Dalton Trans. 2011 Sep 28;40(36):9221-8. doi: 10.1039/c1dt10200a. Epub 2011 Aug 9.
2
2-Acetyl-pyridinium bromanilate.2-乙酰基-吡啶基溴苯胺酸盐
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):o1218. doi: 10.1107/S1600536809016456.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
Hexagonal supramolecular architectures from ferrocenium cations incorporating [Ni(mnt)2]- columns: structures and properties of [alkylferrocene][Ni(mnt)2]- charge-transfer complexes (mnt=maleonitriledithiolate).含[Ni(mnt)₂]柱的二茂铁阳离子形成的六方超分子结构：[烷基二茂铁][Ni(mnt)₂]电荷转移配合物（mnt = 马来二腈二硫醇盐）的结构与性质
Chemistry. 2007;13(6):1872-81. doi: 10.1002/chem.200601275.
5
Crystal engineering using anilic acids and dipyridyl compounds through a new supramolecular synthon.通过一种新型超分子合成子，利用苯胺酸和联吡啶化合物进行晶体工程。
J Org Chem. 2001 Sep 7;66(18):5987-95. doi: 10.1021/jo001746i.