双（乙腈-κN）二氯（η-环辛-1,5-二烯）钌（II）乙腈单溶剂合物
Bis(acetonitrile-κN)dichlorido(η-cyclo-octa-1,5-diene)ruthenium(II) acetonitrile monosolvate.
作者信息
Chiririwa Haleden, Meijboom Reinout, Owalude Samson O, Eke Uche B, Arderne Charmaine
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1096. doi: 10.1107/S1600536811027723. Epub 2011 Jul 16.
In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol-ecule per mol-ecule which is outside the coordination sphere of the ruthenium atom.
在标题钌（II）配合物[RuCl₂(C₈H₁₂)(C₂H₃N)₂]·CH₃CN中，金属离子与环辛二烯配体每个双键的中心、两个氯离子（处于顺式位置）以及两个氮原子供体（来自乙腈分子）配位，从而形成中性配合物的配位球。因此，Ru（II）原子周围的配位可视为具有轻微三角畸变的八面体。每个分子还有一个乙腈溶剂分子位于钌原子的配位球之外。
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