Tafeenko Viktor A, Gurskiy Stanislav I, Aslanov Leonid A
Chemistry Department, Moscow State University, 119991 Moscow, Russian Federation.
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1125-6. doi: 10.1107/S1600536811027309. Epub 2011 Jul 23.
In the title compound, [Cu(ClO(4))(2)(CH(3)CN)(2)(H(2)O)(2)], the Cu(2+) ion, located on a special position (site symmetry [Formula: see text]), is coordinated by six monodentate ligands, viz. an N-coordin-ated acetonitrile, a perchlorate anion and a water mol-ecule, and their symmetry-related counterparts. The perchlorate anion is disordered over two sets of sites with occupancies of 0.53 (2) and 0.47 (2). The crystal structure is stabilized by O-H⋯O hydrogen bonds involving the perchlorate ion and aqua H atoms.
在标题化合物[Cu(ClO₄)₂(CH₃CN)₂(H₂O)₂]中,位于特殊位置(点群对称性[化学式:见原文])的Cu²⁺离子由六个单齿配体配位,即一个N配位的乙腈、一个高氯酸根阴离子和一个水分子,以及它们的对称相关对应物。高氯酸根阴离子在两组位置上无序分布,占有率分别为0.53 (2)和0.47 (2)。晶体结构通过涉及高氯酸根离子和水合氢原子的O—H⋯O氢键得以稳定。