芳烃和杂芳环与二芳基碘𬭩盐的直接芳基化反应，无需使用过渡金属催化剂。
Direct arylation of arene and N-heteroarenes with diaryliodonium salts without the use of transition metal catalyst.
机构信息
Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, PR China.
出版信息
J Org Chem. 2012 Jan 6;77(1):766-71. doi: 10.1021/jo202150t. Epub 2011 Dec 14.
PMID:22136304
Abstract
A novel and simple transition metal-free direct arylation of arene and N-heteroarenes with diaryliodonium salts has been developed. This cross-coupling reaction is promoted only by base and gives the desired products in moderate to good yields.
摘要
一种新型且简便的过渡金属自由的芳基和杂芳基与二芳基碘鎓盐的直接芳基化反应已经被开发出来。这种交叉偶联反应仅在碱的促进下进行，以中等至良好的收率得到所需产物。
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