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法医纤维检验中的二色性测量。第2部分——染色聚酰胺、羊毛和丝绸纤维

Dichroism measurements in forensic fibre examination. Part 2 - dyed polyamide, wool and silk fibres.

作者信息

De Wael K, Vanden Driessche T

机构信息

National Institute for Criminalistics and Criminology, Fibres and Textiles Laboratory, Brussels, Belgium.

出版信息

Sci Justice. 2011 Dec;51(4):163-72. doi: 10.1016/j.scijus.2010.10.005. Epub 2010 Nov 27.

Abstract

A number of dyed polyamide, wool and silk samples were examined with plane polarized light on their dichroic behavior by optical light microscopy (OLM) and microspectrophotometry with plane polarized light (MSP-PPL). It was found that most of these acid dyed peptidic fibres possess dichroism, but these are weaker than the effects previously described for polyester fibres. The small effects may be not observed, especially for wool, but these can be measured using MSP-PPL. In the three peptidic fibre classes, for the first time, a so called "inverse dichroism" is observed which appears in the absorption spectra as a hyperchromic effect.

摘要

通过光学显微镜(OLM)和平面偏振光显微分光光度法(MSP-PPL),用平面偏振光对一些染色的聚酰胺、羊毛和丝绸样品的二向色性行为进行了检测。结果发现,这些酸性染色的肽纤维大多具有二向色性,但比先前描述的聚酯纤维的效应要弱。对于羊毛来说,这种微小的效应可能无法观察到,但可以使用MSP-PPL进行测量。在这三类肽纤维中,首次观察到一种所谓的“反向二向色性”,它在吸收光谱中表现为增色效应。

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