Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apartado 644, E-48080 Bilbao, Spain.
Chem Commun (Camb). 2012 Jan 21;48(6):907-9. doi: 10.1039/c1cc15589j. Epub 2011 Dec 5.
The presence of butanoic acid excess in the reaction media employed for the synthesis of a MOF with formula Cu(2)(μ(3)-ade)(2)(μ(2)-OOC(CH(2))(2)CH(3))(2) (ade: adeninate) leads to the formation of micelles that exert a template effect and provide a pronounced increase of its microporosity, doubling the intrinsic adsorption capacity of the pristine crystal network.
在用于合成具有化学式Cu(2)(μ(3)-ade)(2)(μ(2)-OOC(CH(2))(2)CH(3))(2)（ade：腺嘌呤）的 MOF 的反应介质中存在过量的丁酸会导致形成胶束，这些胶束发挥模板效应，并提供明显增加其微孔率，使原始晶体网络的本征吸附容量增加一倍。
