ACS Appl Mater Interfaces. 2013 Apr 10;5(7):2360-3. doi: 10.1021/am303089g. Epub 2013 Mar 28.
Composite MOF foams were prepared using a direct synthesis of UiO-66 over a polyurethane foam template. Under optimized conditions, the composite materials maintained the macrostructure and flexibility of the polyurethane foam, and exhibited the microporosity, high surface area, and adsorption properties of the UiO-66. The composite MOF foam has hierarchical porosity and high adsorption capacity for benzene and n-hexane, maintaining more than 70% of the adsorption capacity of the UiO-66.
复合 MOF 泡沫是通过在聚氨酯泡沫模板上直接合成 UiO-66 制备的。在优化条件下,复合材料保持了聚氨酯泡沫的宏观结构和柔韧性,并表现出 UiO-66 的微孔、高表面积和吸附性能。复合 MOF 泡沫具有分级多孔结构和对苯和正己烷的高吸附能力,保持了超过 70%的 UiO-66 的吸附能力。