Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, Texas 76019, USA.
Chirality. 2012 Jan;24(1):17-53. doi: 10.1002/chir.21975. Epub 2011 Dec 6.
In recent years, the field of chiral ionic liquids (CILs) has undergone exponential growth. As the technology has advanced, new ways of synthesizing stable and structurally diverse ionic liquids have been established. This has led to heretofore unknown applications of CILs as well as in improving efficiency of previously identified applications. In this review article we have compiled a comprehensive database containing structures and physical properties of notable CILs that have been synthesized during the last 6 years. Their applications in the fields of asymmetric organic synthesis, spectroscopy, and chromatography are also illustrated. This is an expansion of our previous review, which covered the literature before 2005.
近年来,手性离子液体(CILs)领域发展迅速。随着技术的进步,已经建立了合成稳定和结构多样的离子液体的新方法。这导致了 CILs 在以前未知的应用中的应用,以及在提高以前确定的应用的效率方面的应用。在这篇综述文章中,我们汇编了一个综合数据库,其中包含了过去 6 年中合成的著名 CILs 的结构和物理性质。它们在手性有机合成、光谱学和色谱学等领域的应用也得到了说明。这是我们之前的综述的扩展,涵盖了 2005 年之前的文献。