Center for Degradable and Flame-Retardant Polymeric Materials, College of Chemistry, State Key Laboratory of Polymer Materials Engineering, National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), Sichuan University, Chengdu 610064, China.
Biomacromolecules. 2012 Jan 9;13(1):1-11. doi: 10.1021/bm201564a. Epub 2011 Dec 20.
Chitin is the second most abundant semicrystalline polysaccharide. Like cellulose, the amorphous domains of chitin can also be removed under certain conditions such as acidolysis to give rise to crystallites in nanoscale, which are the so-called chitin nanocrystals or chitin whiskers (CHWs). CHW together with other organic nanoparticles such as cellulose whisker (CW) and starch nanocrystal show many advantages over traditional inorganic nanoparticles such as easy availability, nontoxicity, biodegradability, low density, and easy modification. They have been widely used as substitutes for inorganic nanoparticles in reinforcing polymer nanocomposites. The research and development of CHW related areas are much slower than those of CW. However, CHWs are still of strategic importance in the resource scarcity periods because of their abundant availability and special properties. During the past decade, increasing studies have been done on preparation of CHWs and their application in reinforcing polymer nanocomposites. Some other applications such as being used as feedstock to prepare chitosan nanoscaffolds have also been investigated. This Article is to review the recent development on CHW related studies.
几丁质是第二丰富的半晶态多糖。与纤维素一样,几丁质的无定形区也可以在某些条件下(如酸解)被去除,从而在纳米尺度上产生晶畴,即所谓的几丁质纳米晶体或几丁质晶须(CHWs)。CHW 与其他有机纳米粒子(如纤维素晶须(CW)和淀粉纳米晶体)相比,具有许多优于传统无机纳米粒子的优点,如易得性、无毒性、生物降解性、低密度和易于修饰。它们已被广泛用作增强聚合物纳米复合材料中无机纳米粒子的替代品。CHW 相关领域的研究和开发比 CW 慢得多。然而,由于 CHWs 丰富的可用性和特殊性质,在资源短缺时期,它们仍然具有重要的战略意义。在过去的十年中,人们对 CHWs 的制备及其在增强聚合物纳米复合材料中的应用进行了越来越多的研究。一些其他应用,如用作制备壳聚糖纳米支架的原料,也得到了研究。本文综述了 CHW 相关研究的最新进展。