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超越光线限制的太阳能电池光捕获。

Solar Cell light trapping beyond the ray optic limit.

机构信息

Thomas J. Watson Laboratories of Applied Physics, California Institute of Technology, Pasadena, California 91125, USA.

出版信息

Nano Lett. 2012 Jan 11;12(1):214-8. doi: 10.1021/nl203351k. Epub 2012 Jan 3.

Abstract

In 1982, Yablonovitch proposed a thermodynamic limit on light trapping within homogeneous semiconductor slabs, which implied a minimum thickness needed to fully absorb the solar spectrum. However, this limit is valid for geometrical optics but not for a new generation of subwavelength solar absorbers such as ultrathin or inhomogeneously structured cells, wire-based cells, photonic crystal-based cells, and plasmonic cells. Here we show that the key to exceeding the conventional ray optic or so-called ergodic light trapping limit is in designing an elevated local density of optical states (LDOS) for the absorber. Moreover, for any semiconductor we show that it is always possible to exceed the ray optic light trapping limit and use these principles to design a number of new solar absorbers with the key feature of having an elevated LDOS within the absorbing region of the device, opening new avenues for solar cell design and cost reduction.

摘要

1982 年,Yablonovitch 提出了均匀半导体平板内光捕获的热力学限制,这意味着需要一个最小厚度来完全吸收太阳光谱。然而,这个限制对于几何光学是有效的,但对于新一代亚波长太阳能吸收器,如超薄或非均匀结构电池、基于线的电池、基于光子晶体的电池和等离子体电池,则不适用。在这里,我们表明,突破传统光线光学或所谓的遍历光捕获限制的关键在于为吸收器设计一个升高的局域光密度(LDOS)。此外,对于任何半导体,我们都表明,总是有可能突破光线光学光捕获限制,并利用这些原理设计一些新型太阳能吸收器,其关键特征是在器件的吸收区域内具有升高的 LDOS,为太阳能电池设计和成本降低开辟了新的途径。

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