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利用富营养化污水中固定化小球藻去除六价铬的一体化方法。

An integrated approach to remove Cr(VI) using immobilized Chlorella minutissima grown in nutrient rich sewage wastewater.

机构信息

Department of Chemical Engineering, Dr. B.R. Ambedkar National Institute of Technology, Jalandhar 144011, India.

出版信息

Bioresour Technol. 2012 Jan;104:257-65. doi: 10.1016/j.biortech.2011.11.044. Epub 2011 Nov 25.

Abstract

The potential of an integrated system for sewage wastewater treatment and biosorption of chromium(VI) was evaluated using immobilized Chlorella minutissima cells. Immobilized algal cells were grown in sewage wastewater in designed photobioreactor for 48 h and then subjected to removal of Cr(VI) from synthetic wastewater. The effect of pH, Cr(VI) concentration, biosorbent dose on Cr(VI) removal was investigated. C. minutissima showed a higher NH(4)(+)-N and PO(4)(3-)-P removal efficiency (above 99% removal) than the NO(3)(2-)-N (58% removal) in 48 h. Biosorption of Cr(VI) was found to be highly dependent on solution pH, biosorbent dose and initial Cr(VI) concentration. Maximum Cr(VI) uptake 57.33 mg Cr(VI)/g dry biosorbent/L of solution was observed at pH2 with 20% (w/v) biosorbent. Further more than 90% of total Cr adsorbed could be recovered using 0.5 M NaOH as desorption medium.

摘要

利用固定化小球藻细胞评估了污水废水处理和六价铬生物吸附一体化系统的潜力。固定化藻类细胞在设计的光生物反应器中生长 48 小时,然后用于去除合成废水中的六价铬。考察了 pH 值、Cr(VI)浓度、生物吸附剂用量对 Cr(VI)去除的影响。小球藻在 48 小时内对 NH4+-N 和 PO43--P 的去除效率(>99%)高于对 NO32--N 的去除效率(58%)。发现六价铬的生物吸附高度依赖于溶液 pH 值、生物吸附剂用量和初始 Cr(VI)浓度。在 pH2 下,用 20%(w/v)生物吸附剂,最大 Cr(VI)吸附量为 57.33 mg Cr(VI)/g 干生物吸附剂/L。此外,使用 0.5 M NaOH 作为解吸介质可以回收超过 90%的总吸附铬。

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