• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Sustained epoxidation of olefins by oxygen donors catalyzed by transition metal-substituted polyoxometalates, oxidatively resistant inorganic analogs of metalloporphyrins.

作者信息

Hill C L, Brown R B

出版信息

J Am Chem Soc. 1986 Feb 1;108(3):536-8. doi: 10.1021/ja00263a046.

DOI:10.1021/ja00263a046
PMID:22175491
Abstract
摘要

相似文献

1
Sustained epoxidation of olefins by oxygen donors catalyzed by transition metal-substituted polyoxometalates, oxidatively resistant inorganic analogs of metalloporphyrins.
J Am Chem Soc. 1986 Feb 1;108(3):536-8. doi: 10.1021/ja00263a046.
2
Chiral hydroperoxides as oxygen source in the catalytic stereoselective epoxidation of allylic alcohols by sandwich-type polyoxometalates: control of enantioselectivity through a metal-coordinated template.手性氢过氧化物作为夹心型多金属氧酸盐催化烯丙醇立体选择性环氧化反应的氧源：通过金属配位模板控制对映选择性
J Org Chem. 2003 Oct 17;68(21):8222-31. doi: 10.1021/jo034923z.
3
Paramagnetic 1H-NMR relaxation probes of stereoselectivity in metalloporphyrin catalyzed olefin epoxidation.金属卟啉催化烯烃环氧化反应中立体选择性的顺磁1H-NMR弛豫探针
Chirality. 1998;10(1-2):106-19.
4
Enantioselective epoxidation of olefins with chiral metalloporphyrin catalysts.手性金属卟啉催化剂用于烯烃的对映选择性环氧化反应。
Chem Soc Rev. 2005 Jul;34(7):573-83. doi: 10.1039/b405679p. Epub 2005 Apr 18.
5
A highly chemoselective, diastereoselective, and regioselective epoxidation of chiral allylic alcohols with hydrogen peroxide, catalyzed by sandwich-type polyoxometalates: enhancement of reactivity and control of selectivity by the hydroxy group through metal-alcoholate bonding.通过夹心型多金属氧酸盐催化，用过氧化氢对手性烯丙醇进行高度化学选择性、非对映选择性和区域选择性环氧化反应：羟基通过金属醇盐键合增强反应活性并控制选择性。
J Org Chem. 2003 Mar 7;68(5):1721-8. doi: 10.1021/jo0266386.
6
Polyoxometalate catalysts: toward the development of green H2O2-based epoxidation systems.多金属氧酸盐催化剂：迈向基于绿色过氧化氢的环氧化体系的发展
Chem Rec. 2006;6(1):12-22. doi: 10.1002/tcr.20067.
7
Ketone-catalyzed asymmetric epoxidation reactions.酮催化的不对称环氧化反应。
Acc Chem Res. 2004 Aug;37(8):497-505. doi: 10.1021/ar030065h.
8
Theoretical study of photoinduced epoxidation of olefins catalyzed by ruthenium porphyrin.钌卟啉催化烯烃光氧化环化反应的理论研究。
J Phys Chem A. 2011 May 12;115(18):4774-85. doi: 10.1021/jp200650q. Epub 2011 Apr 15.
9
Anthracene-induced turnover enhancement in the manganese porphyrin-catalyzed epoxidation of olefins.蒽对锰卟啉催化烯烃环氧化反应中周转数的增强作用。
Inorg Chem. 2005 Jul 25;44(15):5523-9. doi: 10.1021/ic0505596.
10
Mechanistic insights into alkene epoxidation with H2O2 by Ti- and other TM-containing polyoxometalates: role of the metal nature and coordination environment.通过钛和其他含过渡金属的多金属氧酸盐进行 H2O2 环氧化烯烃的机理研究：金属性质和配位环境的作用。
J Am Chem Soc. 2010 Jun 2;132(21):7488-97. doi: 10.1021/ja1023157.

引用本文的文献

1
Role of Multiple Vanadium Centers on Redox Buffering and Rates of Polyvanadomolybdate-Cu(II)-Catalyzed Aerobic Oxidations.多钒中心在氧化还原缓冲和多钒钼酸铜(II)-催化有氧氧化速率中的作用。
Inorg Chem. 2023 Apr 10;62(14):5822-5830. doi: 10.1021/acs.inorgchem.3c00469. Epub 2023 Mar 28.
2
Porous metalloporphyrinic nanospheres constructed from metal 5,10,15,20-tetraksi(4'-ethynylphenyl)porphyrin for efficient catalytic degradation of organic dyes.由金属5,10,15,20-四（4'-乙炔基苯基）卟啉构建的多孔金属卟啉纳米球用于有机染料的高效催化降解。
RSC Adv. 2018 Feb 15;8(14):7330-7339. doi: 10.1039/c7ra12701d. eCollection 2018 Feb 14.
3
DFT study of α-Keggin, lacunary Keggin, and iron substituted Keggin polyoxometalates: the effect of oxidation state and axial ligand on geometry, electronic structures and oxygen transfer.
α-凯琴、缺位凯琴和铁取代凯琴多金属氧酸盐的密度泛函理论研究：氧化态和轴向配体对几何结构、电子结构及氧转移的影响
RSC Adv. 2020 Sep 11;10(56):33718-33730. doi: 10.1039/d0ra05189f. eCollection 2020 Sep 10.
4
Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate Framework.多氟氧金属酸盐骨架中稳定的 Mn(IV)-和 Mn(V)-羟基物种的反应活性及氧气生成
J Am Chem Soc. 2015 Jul 15;137(27):8738-48. doi: 10.1021/jacs.5b03456. Epub 2015 Jun 29.
5
Di-μ-acetato-κ(4) O:O'-bis-[(1,10-phenanthroline-κ(2) N,N')(tri-fluoro-methane-sulfonato-κO)copper(II)].二-μ-乙酸根-κ(4) O:O'-双-[(1,10-菲咯啉-κ(2) N,N')(三氟甲磺酸根-κO)铜(II)]
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 12;69(Pt 11):m591-2. doi: 10.1107/S1600536813027323.
6
Preparation and Electrocatalytic Application of Composites Containing Gold Nanoparticles Protected with Rhodium-Substituted Polyoxometalates.含铑取代多金属氧酸盐保护的金纳米粒子复合材料的制备及其电催化应用
Electrochim Acta. 2011 Apr 1;56(10):3537-3542. doi: 10.1016/j.electacta.2010.09.039.