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机械连接:一件艺术品。

The mechanical bond: a work of art.

作者信息

Bruns Carson J, Stoddart J Fraser

机构信息

Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.

出版信息

Top Curr Chem. 2012;323:19-72. doi: 10.1007/128_2011_296.

Abstract

Mechanically interlocked objects are ubiquitous in our world. They can be spotted on almost every scale of matter and in virtually every sector of society, spanning cultural, temporal, and physical boundaries the world over. From art to machinery, to biological entities and chemical compounds, mechanical interlocking is being used and admired every day, inspiring creativity and ingenuity in art and technology alike. The tiny world of mechanically interlocked molecules (MIMs), which has been established and cultivated over the past few decades, has connected the ordinary and molecular worlds symbolically with creative research and artwork that subsumes the molecular world as a miniaturization of the ordinary one. In this review, we highlight how graphical representations of MIMs have evolved to this end, and discuss various other aspects of their beauty as chemists see them today. We argue that the many aspects of beauty in MIMs are relevant, not only to the pleasure chemists derive from their research, but also to the progress of the research itself.

摘要

机械互锁的物体在我们的世界中无处不在。它们几乎可以在物质的各个尺度上被发现,并且实际上存在于社会的各个领域,跨越了世界各地的文化、时间和物理界限。从艺术到机械,再到生物实体和化合物,机械互锁每天都在被使用和欣赏,激发着艺术和技术领域的创造力和独创性。在过去几十年中建立和发展起来的机械互锁分子(MIMs)的微观世界,通过创造性的研究和将分子世界视为普通世界的缩影的艺术作品,象征性地将普通世界与分子世界联系起来。在这篇综述中,我们强调了MIMs的图形表示是如何为此目的而发展的,并讨论了从当今化学家的视角来看它们的美的其他各个方面。我们认为,MIMs之美的许多方面不仅与化学家从研究中获得的乐趣相关,而且与研究本身的进展相关。

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