混合价态的单金属和杂金属网格索烃。
Mixed valence mono- and hetero-metallic grid catenanes.
作者信息
Giri Chandan, Topić Filip, Cametti Massimo, Rissanen Kari
机构信息
University of Jyvaskyla , Department of Chemistry , Nanoscience Center , P. O. Box. 35, FI-40014 University of Jyvaskyla , Finland . Email:
Department of Chemistry , Materials and Chemical Engineering "Giulio Natta" , Politecnico di Milano , Via L. Mancinelli 7 , 20131 Milano , Italy . Email:
出版信息
Chem Sci. 2015 Oct 1;6(10):5712-5718. doi: 10.1039/c5sc01851j. Epub 2015 Jun 30.
Here, we report on the multicomponent self-assembly and single crystal X-ray diffraction study of a series of three interlocked mixed valence mono- and hetero-metallic [2]-catenanes made of [2 × 2] metallo-grids. They show unique structural features and highlight the essential roles of both the Cu(ii)/Cu(i) pair and of the conformationally adaptable organic ligands for achieving catenation of grids.
在此，我们报告了一系列由[2×2]金属网格构成的三个互锁的混合价单金属和杂金属[2]连环烷的多组分自组装及单晶X射线衍射研究。它们展现出独特的结构特征，并突出了Cu(ii)/Cu(i)对以及构象适应性有机配体在实现网格连环化过程中的重要作用。
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