• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

四水双[1-(3-羧基苯基)-4,4'-联吡啶-1-鎓-κN]锌双(4,5-羧基苯-1,2-二羧酸)2.5水合物

Tetra-aqua-bis-[1-(3-carb-oxy-phen-yl)-4,4'-bipyridin-1-ium-κN]zinc bis-(4,5-carb-oxy-benzene-1,2-dicarboxyl-ate) 2.5-hydrate.

作者信息

Zhang Jie, Tan Yi, Fu Zhiyong

机构信息

Key Lab for Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1701-2. doi: 10.1107/S1600536811045156. Epub 2011 Nov 5.

DOI:10.1107/S1600536811045156
PMID:22199517
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238626/
Abstract

In the complex cation of the title compound, Zn(C(17)H(13)N(2)O(2))(2)(H(2)O)(4)(2)·2.5H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N-(3-carb-oxy-phen-yl)-4,4'-bipyridin-1-ium ligands and four water mol-ecules in a distorted octa-hedral geometry. The pyromellitate anion is double deprotonated. O-H⋯O and C-H⋯O hydrogen bonds connect the cations, anions and uncoordinated water mol-ecules into a three-dimensional supra-molecular network. One of the two lattice water molecules shows an occupancy of 0.25. An intra-molecular O-H⋯O hydrogen bond is present in the anion.

摘要

在标题化合物Zn(C₁₇H₁₃N₂O₂)₂(H₂O)₄₂·2.5H₂O的络合阳离子中，位于对称中心的Zn(II)原子由来自两个N-(3-羧基苯基)-4,4'-联吡啶-1-鎓配体的两个N原子和四个水分子以扭曲的八面体几何构型配位。均苯四甲酸根阴离子是双去质子化的。O-H⋯O和C-H⋯O氢键将阳离子、阴离子和未配位的水分子连接成三维超分子网络。两个晶格水分子中的一个占有率为0.25。阴离子中存在分子内O-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248c/3238626/ebcb8df157a5/e-67-m1701-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248c/3238626/e499fe47e9f2/e-67-m1701-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248c/3238626/ebcb8df157a5/e-67-m1701-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248c/3238626/e499fe47e9f2/e-67-m1701-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248c/3238626/ebcb8df157a5/e-67-m1701-fig2.jpg

相似文献

1
Tetra-aqua-bis-[1-(3-carb-oxy-phen-yl)-4,4'-bipyridin-1-ium-κN]zinc bis-(4,5-carb-oxy-benzene-1,2-dicarboxyl-ate) 2.5-hydrate.四水双[1-(3-羧基苯基)-4,4'-联吡啶-1-鎓-κN]锌双(4,5-羧基苯-1,2-二羧酸)2.5水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1701-2. doi: 10.1107/S1600536811045156. Epub 2011 Nov 5.
2
Tetra-aqua-bis-{3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzoato-κO}cobalt(II) dihydrate.二水合四水双-{3-羧基-5-[(4-羧基苯基)重氮基]苯甲酸根-κO}钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1689. doi: 10.1107/S1600536811045557. Epub 2011 Nov 5.
3
Poly[[diaqua-bis-{μ-4-[6-(4-carb-oxy-phen-yl)-4,4'-bipyridin-2-yl]benzoato-κ(2) O:N (1')}copper(II)] dimethyl-formamide tetra-solvate].聚[[二水合双-{μ-4-[6-(4-羧基苯基)-4,4'-联吡啶-2-基]苯甲酸根-κ(2) O:N (1')}铜(II)] 二甲基甲酰胺四溶剂合物]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 13;69(Pt 4):m202-3. doi: 10.1107/S1600536813006430. Print 2013 Apr 1.
4
Tetra-aqua-bis-[N,N'-bis-(pyridin-3-yl-methyl-idene)benzene-1,4-diamine]-zinc dinitrate 1.49-hydrate.二硝酸四水合双-[N,N'-双-(吡啶-3-基-亚甲基)苯-1,4-二胺]锌1.49水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1752. doi: 10.1107/S1600536811046915. Epub 2011 Nov 12.
5
Aqua-(4-bromo-benzoato-κO)bis-(1,10-phenanthroline-κN,N')zinc(II) 4-bromo-benzoate 1.5-hydrate.水合（对溴苯甲酸根-κO）双（1,10-菲咯啉-κN,N'）锌（II）对溴苯甲酸酯1.5水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 2;66(Pt 11):m1357-8. doi: 10.1107/S160053681003864X.
6
Diaqua-(5-carb-oxy-benzene-1,3-dicarboxyl-ato-κO,O)(6,6'-dimethyl-2,2'-bipyridine-κN,N')nickel(II) hepta-hydrate.二水合 -（5 - 羧基 - 苯 - 1,3 - 二羧酸根合 -κO,O）（6,6'- 二甲基 - 2,2'- 联吡啶 -κN,N'）镍（II）七水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1244-5. doi: 10.1107/S1600536811032090. Epub 2011 Aug 17.
7
Bis[tetra-aqua-(1,10-phenanthroline-κN,N')cobalt(II)] hexa-aqua-cobalt(II) bis-[3,5-bis-(carboxyl-atometh-oxy)benzoate] tetra-hydrate.双[四水合-(1,10-菲咯啉-κN,N')钴(II)]六水合钴(II)双[3,5-双-(羧基甲氧基)苯甲酸酯]四水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 17;66(Pt 12):m1577-8. doi: 10.1107/S1600536810046386.
8
Diaqua-bis-(5-carb-oxy-2-ethyl-1H-imidazole-5-carboxyl-ato-κN,O)zinc trihydrate.三水合二水双（5-羧基-2-乙基-1H-咪唑-5-羧基根合-κN,O）锌
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m717. doi: 10.1107/S160053681101676X. Epub 2011 May 7.
9
2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb-oxy-4-hy-droxy-pyridine-2-carboxyl-ato-κO,N,O)(4-hy-droxy-pyridine-2,6-dicarboxyl-ato-κO,N,O)nickelate(II) 2.35-hydrate: a proton-transfer compound.2,9 - 二甲基 - 1,10 - 菲啰啉鎓（6 - 羧基 - 4 - 羟基 - 吡啶 - 2 - 羧酸根 - κO,N,O）（4 - 羟基 - 吡啶 - 2,6 - 二羧酸根 - κO,N,O）镍酸盐（II）2.35水合物：一种质子转移化合物。
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 11;66(Pt 9):m1084-5. doi: 10.1107/S1600536810031399.
10
2',6'-Bis(4-carb-oxy-phen-yl)-4,4'-bipyridin-1-ium nitrate 0.25-hydrate.2',6'-双(4-羧基苯基)-4,4'-联吡啶鎓硝酸盐0.25水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):o43. doi: 10.1107/S1600536811051506. Epub 2011 Dec 7.

本文引用的文献

1
Conformational and photosensitive adjustment of the 4,4'-bipyridinium in Mn(II) coordination complexes.锰(II)配位化合物中 4,4'-联吡啶的构象和光响应性的调节。
Chem Commun (Camb). 2010 Jul 14;46(26):4695-7. doi: 10.1039/c0cc00135j. Epub 2010 Jun 3.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Photochromism of a methyl viologen bismuth(III) chloride: structural variation before and after UV irradiation.
Angew Chem Int Ed Engl. 2007;46(18):3249-51. doi: 10.1002/anie.200700122.