Caracelli Ignez, Zukerman-Schpector Julio, Machado André T Lousada, Brocksom Timothy J, Ferreira M Lúcia, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3338. doi: 10.1107/S1600536811048008. Epub 2011 Nov 16.
In the title compound, C(19)H(28)O(2), the A ring adopts a chair conformation. Both the B and C rings adopt envelope conformations with the C atoms common to both rings and adjacent to the carbonyl and hydroxyl groups, respectively, lying 0.604 (3) and 0.634 (3) Å out of the mean planes defined by the remaining five C atoms of rings B and C, respectively (r.m.s. deviations = 0.0100 and 0.0157 Å, respectively). The formation of linear supra-molecular C(7) chains along the a axis mediated by hy-droxy-O-H⋯O(carbon-yl) hydrogen bonds is the most prominent feature of the crystal packing.
在标题化合物C(19)H(28)O(2)中,A环呈椅式构象。B环和C环均呈信封式构象,两个环共有的且分别与羰基和羟基相邻的C原子,相对于由环B和环C其余五个C原子所定义的平均平面,分别偏离0.604 (3) Å和0.634 (3) Å(均方根偏差分别为0.0100 Å和0.0157 Å)。由羟基O—H⋯O(羰基)氢键介导沿a轴形成线性超分子C(7)链是晶体堆积的最显著特征。