3-氯-N-(2-甲基苯基)苯甲酰胺
3-Chloro-N-(2-methyl-phen-yl)benzamide.
作者信息
Rodrigues Vinola Z, Herich Peter, Gowda B Thimme, Kožíšek Jozef
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3381. doi: 10.1107/S1600536811048756. Epub 2011 Nov 19.
Abstract
In the mol-ecular structure of the title compound, C(14)H(12)ClNO, the meta-Cl atom in the benzoyl ring is positioned anti to the C=O bond, while the ortho-methyl group in the aniline ring is positioned syn to the N-H bond. The two benzene rings are nearly coplanar [dihedral angle = 3.48 (5)°]. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which link the mol-ecules into chains along the b axis.
摘要
在标题化合物C(14)H(12)ClNO的分子结构中，苯甲酰环上的间位氯原子与C=O键呈反式排列，而苯胺环上的邻位甲基与N-H键呈顺式排列。两个苯环几乎共面[二面角 = 3.48 (5)°]。晶体结构通过N-H⋯O氢键得以稳定，这些氢键将分子沿b轴连接成链。
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