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实际发动机负荷条件对配备有 DPF 和 SCR 的重型柴油发动机纳米颗粒排放的影响。

Influence of real-world engine load conditions on nanoparticle emissions from a DPF and SCR equipped heavy-duty diesel engine.

机构信息

Mechanical and Aerospace Department, West Virginia University, Morgantown, West Virginia 26505, United States of America.

出版信息

Environ Sci Technol. 2012 Feb 7;46(3):1907-13. doi: 10.1021/es203079n. Epub 2012 Jan 13.

Abstract

The experiments aimed at investigating the effect of real-world engine load conditions on nanoparticle emissions from a Diesel Particulate Filter and Selective Catalytic Reduction after-treatment system (DPF-SCR) equipped heavy-duty diesel engine. The results showed the emission of nucleation mode particles in the size range of 6-15 nm at conditions with high exhaust temperatures. A direct result of higher exhaust temperatures (over 380 °C) contributing to higher concentration of nucleation mode nanoparticles is presented in this study. The action of an SCR catalyst with urea injection was found to increase the particle number count by over an order of magnitude in comparison to DPF out particle concentrations. Engine operations resulting in exhaust temperatures below 380 °C did not contribute to significant nucleation mode nanoparticle concentrations. The study further suggests the fact that SCR-equipped engines operating within the Not-To-Exceed (NTE) zone over a critical exhaust temperature and under favorable ambient dilution conditions could contribute to high nanoparticle concentrations to the environment. Also, some of the high temperature modes resulted in DPF out accumulation mode (between 50 and 200 nm) particle concentrations an order of magnitude greater than typical background PM concentrations. This leads to the conclusion that sustained NTE operation could trigger high temperature passive regeneration which in turn would result in lower filtration efficiencies of the DPF that further contributes to the increased solid fraction of the PM number count.

摘要

本实验旨在研究实际发动机负荷条件对配备有柴油颗粒过滤器和选择性催化还原后处理系统(DPF-SCR)的重型柴油机的纳米颗粒排放的影响。结果表明,在废气温度较高的条件下,会排放出 6-15nm 范围内的成核模态粒子。本研究直接表明,较高的废气温度(超过 380°C)会导致成核模态纳米粒子的浓度更高。与 DPF 外颗粒浓度相比,添加尿素的 SCR 催化剂的作用会使颗粒数计数增加一个数量级以上。导致废气温度低于 380°C 的发动机运行不会导致显著的成核模态纳米颗粒浓度。研究进一步表明,在临界废气温度和有利的环境稀释条件下,在不超过(Not-To-Exceed,NTE)限值的范围内运行的配备 SCR 的发动机可能会导致环境中纳米颗粒浓度升高。此外,一些高温模式导致 DPF 外积累模式(50nm 至 200nm 之间)颗粒浓度比典型背景 PM 浓度高一个数量级。这得出的结论是,持续的 NTE 操作可能会引发高温被动再生,从而导致 DPF 的过滤效率降低,这进一步导致 PM 数量计数的固体分数增加。

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