School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, United Kingdom.
Langmuir. 2012 Feb 7;28(5):2502-9. doi: 10.1021/la204557t. Epub 2012 Jan 19.
For the first time a series of anionic surfactant ionic liquids (SAILs) has been synthesized based on organic surfactant anions and 1-butyl-3-methyl-imidazolium cations. These compounds are more environmentally friendly and chemically tunable as compared to other common ionic liquids. A detailed investigation of physicochemical properties highlights potential applications from battery design to reaction control, and studies into aqueous aggregation behavior, as well as structuring in pure ILs, point to possible uses in electrochemistry.
首次合成了一系列基于有机表面活性剂阴离子和 1-丁基-3-甲基咪唑阳离子的阴离子型表面活性剂离子液体(SAILs)。与其他常见的离子液体相比,这些化合物更环保且化学可调。对物理化学性质的详细研究突出了其在电池设计到反应控制等方面的潜在应用,并对水相聚集行为以及纯离子液体中的结构进行了研究,指出了它们在电化学中的可能用途。