四氟化锗（IV）和四氟化锡（IV）与环状和非环状碳烯的配合物：二（二烷基氨基）-二氟亚甲基作为碳烯源。
Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources.
机构信息
School of Engineering and Science, Jacobs University Bremen, Campus Ring 1, 28759 Bremen, Germany.
出版信息
Inorg Chem. 2012 Jan 16;51(2):763-5. doi: 10.1021/ic202008m. Epub 2012 Jan 3.
PMID:22216889
Abstract
Carbene complexes of Ge(IV)- and Sn(IV)-fluorides have been synthesized by oxidative addition of 2,2-difluoro-1,3-dimethylimidazolidine and bis(dimethylamino)difluoromethane to GeCl(2)•dioxane and SnF(2). Chloride analogs of the Ge(IV) complexes were also isolated. All compounds were characterized in the solid state by single-crystal X-ray diffraction.
摘要
通过将 2,2-二氟-1,3-二甲基咪唑烷和双(二甲氨基)二氟甲烷氧化加成到 GeCl2•二氧六环和 SnF2 中，合成了 Ge(IV)-和 Sn(IV)-氟化物的卡宾配合物。还分离出了 Ge(IV)配合物的氯化物类似物。所有化合物均通过单晶 X 射线衍射在固态下进行了表征。
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