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N'-(4-氯-亚苄基)-2-[4-(甲硫基)苯基]乙酰肼

N'-(4-Chloro-benzyl-idene)-2-[4-(methyl-sulfan-yl)phen-yl]acetohydrazide.

作者信息

Fun Hoong-Kun, Hemamalini Madhukar, Sumangala V, Prasad D Jagadeesh, Poojary Boja

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2847. doi: 10.1107/S1600536811039857. Epub 2011 Oct 5.

Abstract

In the title compound, C(16)H(15)ClN(2)OS, the hydrazine group is twisted slightly: the C-N-N-C torsion angle is 175.46 (13)°. The dihedral angle between the two terminal aromatic rings is 87.01 (8)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops. The dimers are further linked by weak C-H⋯π inter-actions.

摘要

在标题化合物C(16)H(15)ClN(2)OS中,肼基略有扭曲:C-N-N-C扭转角为175.46 (13)°。两个末端芳香环之间的二面角为87.01 (8)°。在晶体中,由N-H⋯O氢键对连接的反演二聚体形成R(2) (2)(8)环。二聚体通过弱C-H⋯π相互作用进一步连接。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8eb/3247585/816372b6e19b/e-67-o2847-fig1.jpg

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