Department of Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States.
ACS Nano. 2012 Feb 28;6(2):1479-85. doi: 10.1021/nn2043548. Epub 2012 Jan 17.
Free-standing nanorod arrays of poly(3-hexylthiophene) (P3HT) were fabricated on indium tin oxide/glass substrates using anodic aluminum oxide (AAO) templates. The AAO templates were treated with a low molecular weight polydimethylsiloxane mold-release agent to reduce their surface energy of the template and interactions with the P3HT. Using a thermal nanoimprinting process, the templates were easily removed, generating nanorods on the surfaces of P3HT thin films. These unique structures were investigated for application in organic photovoltaic devices.
采用阳极氧化铝(AAO)模板在铟锡氧化物/玻璃基底上制备了聚(3-己基噻吩)(P3HT)独立纳米棒阵列。为了降低模板的表面能和与 P3HT 的相互作用,用低分子量聚二甲基硅氧烷脱模剂对 AAO 模板进行了处理。采用热压印工艺,模板很容易被去除,在 P3HT 薄膜表面生成纳米棒。这些独特的结构被应用于有机光伏器件进行了研究。