环庚-1,3,5-三烯及其杂元素类似物的价态异构化。
Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues.
机构信息
Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands.
出版信息
Beilstein J Org Chem. 2011;7:1713-21. doi: 10.3762/bjoc.7.201. Epub 2011 Dec 21.
Abstract
The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications.
摘要
综述了全碳和杂元素类似物的环庚-1,3,5-三烯的价态异构化为相应的双环[4.1.0]庚-2,4-二烯，以表明杂原子对两种价态异构体稳定性的影响。重点是母体系统及其合成应用。
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